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Confined phosphorus in carbon nanotube-backboned mesoporous carbon as superior anode material for sodium/potassium-ion batteries

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成果类型:
期刊论文
作者:
Liu, Dan;Huang, Xingkang;Qu, Deyu;Zheng, Dong;Wang, Gongwei;...
通讯作者:
Qu, Deyang
作者机构:
[Qu, Deyu; Qu, Deyang; Liu, Dan] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Dept Chem, 122 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China.
[Zheng, Dong; Wang, Gongwei; Si, Jingyu; Ding, Tianyao; Qu, Deyang; Harris, Joshua; Chen, Junhong; Huang, Xingkang; Liu, Dan] Univ Wisconsin, Coll Engn & Appl Sci, Dept Mech Engn, 3200 N Cramer St, Milwaukee, WI 53211 USA.
通讯机构:
[Qu, Deyang] W
[Qu, Deyang] U
Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Dept Chem, 122 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China.
Univ Wisconsin, Coll Engn & Appl Sci, Dept Mech Engn, 3200 N Cramer St, Milwaukee, WI 53211 USA.
语种:
英文
关键词:
Carbon;Cyclic performance;Phosphorus;Potassium-ion battery;Rate capability;Sodium-ion battery
期刊:
Nano Energy
ISSN:
2211-2855
年:
2018
卷:
52
页码:
1-10
基金类别:
As illustrated in Fig. 1, the TBMC materials were fabricated through a one-pot sol-gel coating method, using TEOS as a porogen agent and resorcinol-formaldehyde (RF) as a carbon precursor. When TEOS, R, and F were added to a CNT dispersion in an ammonia-ethanol-water mixture, two stӧber reactions (i.e., hydrolysis/polymerization of TEOS and polymerization of RF) occurred [45], [46], respectively, producing SiO2 and RF resin phases deposited onto the surface of CNTs by their individual
机构署名:
本校为第一且通讯机构
院系归属:
化学化工与生命科学学院
摘要:
Sodium and potassium ion batteries (SIBs and PIBs) hold promise as potential low-cost and large-scale energy storage devices due to the earth abundance of sodium and potassium. Among all proposed anode materials, red phosphorus (P) has been recognized as a promising candidate owing to its high theoretical capacities for use in both SIBs and PIBs (2596 mA h g−1 for Na3P and 843 mA h g−1 for KP);however, its intrinsic insulating property and large volume change during cycling lead to poor cycling and rate performance. To overcome these issues, we have designed and synthesized a carbo...

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