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Twinned Tungsten Carbonitride Nanocrystals Boost Hydrogen Evolution Activity and Stability

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成果类型:
期刊论文
作者:
Kou, Zongkui*;Wang, Tingting;Wu, Haijun;Zheng, Lirong;Mu, Shichun;...
通讯作者:
Kou, Zongkui;Pennycook, Stephen J.;Wang, John
作者机构:
[Pan, Zhenghui; Wang, John; Pennycook, Stephen J.; Lyu, Zhiyang; Kou, ZK; Wang, J; Wu, Haijun; Kou, Zongkui; Zang, Wenjie] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117574, Singapore.
[Wang, Tingting; Mu, Shichun] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China.
[Zheng, Lirong] Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China.
通讯机构:
[Kou, ZK; Pennycook, SJ; Wang, J] N
Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117574, Singapore.
语种:
英文
关键词:
DFT calculations;hydrogen evolution;tungsten carbonitride;twinned structures;XANES
期刊:
Small
ISSN:
1613-6810
年:
2019
卷:
15
期:
19
页码:
e1900248
基金类别:
Z. K. and T. W. contributed equally to this work. The authors thank the support of MOE (MOE2016-T2-2-138, Singapore) for funding of the research, conducted at the Singapore University of Singapore.
机构署名:
本校为其他机构
院系归属:
材料复合新技术国家重点实验室
摘要:
Synergistic integration of two active metal-based compounds can lead to much higher electrocatalytic activity than either of the two individually, due to the interfacial effects. Herein, a proof-of-concept strategy is creatively developed for the successful fabrication of twinned tungsten carbonitride (WCN) nanocrystals, where W 2 C and WN are chemically bonded at the molecule level. High-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and X-ray absorption fine structure (XAFS) spectroscopy analyses demonstrate t...

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