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In situ growth of Co3O4 on nitrogen-doped hollow carbon nanospheres as air electrode for lithium-air batteries

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成果类型:
期刊论文
作者:
Wang, Junbo;Fan, Meiling;Tu, Wenmao*;Chen, Kai;Shen, Yafei;...
通讯作者:
Tu, Wenmao;Zhang, Haining
作者机构:
[Tu, WM; Zhang, HN; Tu, Wenmao; Fan, Meiling; Zhang, Haining; Wang, Junbo] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China.
[Chen, Kai; Shen, Yafei] Wuhan Jingce Elect Technol Co, Wuhan 430070, Hubei, Peoples R China.
通讯机构:
[Tu, WM; Zhang, HN] W
Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China.
语种:
英文
关键词:
Li-O-2 battery;Bifunctional catalysts;Nitrogen-doped hollow carbon nanospheres;Transition metal oxide;Air electrode
期刊:
Journal of Alloys and Compounds
ISSN:
0925-8388
年:
2019
卷:
777
页码:
944-953
基金类别:
Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21576216, 21878239]; International Cooperation and Exchanges Projects of Hubei Province [2017AHB057]
机构署名:
本校为第一且通讯机构
院系归属:
材料复合新技术国家重点实验室
摘要:
Design and synthesis of efficient bifunctional electrocatalysts for both oxygen reduction reaction and oxygen evolution reactions are of great significant for metal-air batteries. In this work, bifunctional catalysts consisting of Co3O4 nanocrystals and nitrogen-doped hollow carbon nanospheres are synthesized through in situ growth of Co3O4 nanocrystals on the surface of nitrogen-doped hollow carbon nanospheres. The observed Co–N bond formation is an indication of the nucleation of Co3O4 nanocrystals starting from N-sites in nitrogen-doped hollow carbon nanospheres. The resulted hybrids ...

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